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Table 1 Chemical-mineralogical components and physical-mechanical values of selected bedding and pointing mortars from the Ming Great Wall

From: Types of lime binders in mortars used for the construction of the Ming Great Wall of China and their importance for the development of a conservation strategy

Sample Province

Location

name

Mortar type

Chemical Composition (Wt.-%)

Component

Aggregate/Grain size distribution

Water absorption

Bulk density

Lime-type

Orig. binder

B/Aa)

B/Ab)

Hydraul. compon. (binder)

CaO

MgO

Main components

Ancillary components

Main Minerals

Mesh size (mm) through fraction (wt.%)

Wt.-%

Vol%

g/cm3

(DIN-EN*)

Hebei

Simatai

SMT

bedding mortar

94.68

1: 0.05

1: 0.07

<  0.1

31.73**

20.76 **

CaCO3, MgCO3

CaCO3

(aragonite)

SiO2 (quartz)

quartz

0.063-47%

0.125-72%

0.25-84%

0.5-100%

19.47

33.32

1.72

DL 80-30

Hebei Jiang maoyu JMY

bedding mortar

97.66

1: 0.02

1: 0.05

1.4

30.36

15.52

CaCO3, Mg5(CO3)4(OH)2*4H2O (hy-dromagne-site), MgCO3

CaCO3

(aragonite)

SiO2 (quartz)

quartz, silicates (bricks) feldspars, mica, coal

0.063-68%

0.125-89%

0.25-100%

17.63

29.81

1.69

DL90-30

Shanxi Xinguangwu XGWD

bedding mortar

82.53

1: 0.17

1: 0.19

3.52

49.81

1.06

CaCO3

SiO2 (quartz) CaSO4·2H2O (gypsum)

quartz, coal

0.063-48%

0.125-66%

0.25-85%

0.5-100%

42.32

48.95

1.16

CL80

Shanxi Xinguangwu XGWF

pointing mortar

81.66

1: 0.18

1: 0.15

5.98

49.39

1.26

CaCO3

CaCO3 (ara-gonite)

Al2SiO5 (cya-nite), SiO2 (quartz)CSH?

quartz, silicates (bricks) feldspars, mica, coal

0.063-55%

0.125-80%

0.25-93%

0.5-100%

44.58

49.58

1.11

NHL 2/CL80

  1. B/Aa): determined by common combined chemical and mineralogical analytical procedures (Middendorf et al. 2005a, 2005b, 2005c)
  2. B/Ab): determined by Digital Image Analyse (DIA) (Middendorf et al. 2017) based on images of thin sections
  3. *Estimated lime-type based on DIN EN 459-1: 2015-07
  4. **These values were recalculated from almost exclusively available CaCO3 and MgCO3
  5. Source: wet-chemical investigations by CAUP, Tongji University and verified by wet chemical and mineralogical investigations at the University of Kassel and the Institut fĂĽr Steinkonservierung, Mainz